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S Sulfur-Nitrogen Compounds
Part 10a: Compounds with Sulfur of Oxidation Number II
Norbert Baumann, Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny
Livre broché | Anglais | Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition | S. Schwefel. Sulfur (System-Nr. 9)
93,45 €
+ 186 points
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Description
The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida- tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or- ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi- tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one- coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR, R = organyl). Only the reac- 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.
Spécifications
Parties prenantes
- Auteur(s) :
- Editeur:
Contenu
- Nombre de pages :
- 324
- Langue:
- Anglais
- Collection :
Caractéristiques
- EAN:
- 9783662063538
- Date de parution :
- 03-10-13
- Format:
- Livre broché
- Format numérique:
- Trade paperback (VS)
- Dimensions :
- 178 mm x 254 mm
- Poids :
- 612 g
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